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By editing the registry, you can remove Network Neighborhood icon from your desktop. Just follow the below steps:

• Go to Start Button and open Run then type: regedit
• Go to HKey_Current_User \ Software\ Microsoft \Windows \ Current Version \ Policies \ Explorer
• Right click on the right panel and add a New / DWORD
• Name it NoNetHood
• Give it a value of 1

Now, when you Logoff or Reboot the computer, "Network Neighborhood" icon will not be there.